Please use this identifier to cite or link to this item: https://dspace.univ-ouargla.dz/jspui/handle/123456789/6488
Title: ANODIC BEHAVIOUR INVESTIGATION OF (FERROCENYLMETHYL) TRIMETHYLAMMONIUM CATION
Authors: B. TERKI
T. LANEZ
Keywords: Ferrocene
ferrocenylmethyltrimethyammonium iodide
dimethylaminomethylferrocene
NMR
Redox behaviour
cyclic voltammetry
Issue Date: 2007
Series/Report no.: volume 1 numéro 2 AST 2007;
Abstract: The quaternary ammonium salt (ferrocenylmethyl)trimethylammonium iodide 4 containing an amminomethyl group has been prepared by the amminomethylation of ferrocene 1 with the Mannich reagent followed by quaternisation with iodomethane. The obtained tertiary ammine 3 and its methiodide 4 have been characterized by FTIR, 1H NMR and 13C NMR. Their electrochemical behaviours have been investigated by cyclic voltammetry, indicating that the quaternary salt 4 exhibit reversible one-electron oxidations of the ferrocene moiety, which is influenced by the aminomethyl group introduced to the ferrocene centre. The same remakes were observed even at slow scan rates.
Description: AST Annales des Sciences et Technologie
URI: http://dspace.univ-ouargla.dz/jspui/handle/123456789/6488
ISSN: 2170-0672
Appears in Collections:volume 1 numéro 2 AST 2007

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