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Title: | ANODIC BEHAVIOUR INVESTIGATION OF (FERROCENYLMETHYL) TRIMETHYLAMMONIUM CATION |
Authors: | B. TERKI T. LANEZ |
Keywords: | Ferrocene ferrocenylmethyltrimethyammonium iodide dimethylaminomethylferrocene NMR Redox behaviour cyclic voltammetry |
Issue Date: | 2007 |
Series/Report no.: | volume 1 numéro 2 AST 2007; |
Abstract: | The quaternary ammonium salt (ferrocenylmethyl)trimethylammonium iodide 4 containing an amminomethyl group has been prepared by the amminomethylation of ferrocene 1 with the Mannich reagent followed by quaternisation with iodomethane. The obtained tertiary ammine 3 and its methiodide 4 have been characterized by FTIR, 1H NMR and 13C NMR. Their electrochemical behaviours have been investigated by cyclic voltammetry, indicating that the quaternary salt 4 exhibit reversible one-electron oxidations of the ferrocene moiety, which is influenced by the aminomethyl group introduced to the ferrocene centre. The same remakes were observed even at slow scan rates. |
Description: | AST Annales des Sciences et Technologie |
URI: | http://dspace.univ-ouargla.dz/jspui/handle/123456789/6488 |
ISSN: | 2170-0672 |
Appears in Collections: | volume 1 numéro 2 AST 2007 |
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File | Description | Size | Format | |
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A010215.pdf | 174,93 kB | Adobe PDF | View/Open |
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