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DC Field | Value | Language |
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dc.contributor.author | M.S.NEDJIMI, and Lakhdar SEKHRI | - |
dc.date.accessioned | 2013-12-19T15:00:19Z | - |
dc.date.available | 2013-12-19T15:00:19Z | - |
dc.date.issued | 2013-12-19 | - |
dc.identifier.issn | saf | - |
dc.identifier.uri | http://hdl.handle.net/123456789/2815 | - |
dc.description | 1st International Days of Organometallic Chemistry and Catalysis JICOC Ouargla, February 06- 09, 2012 | en_US |
dc.description.abstract | A range of prochiral acetophenone derivatives have been converted efficiently to the corresponding (R)- alcohols with > 80% yield and good enantioselectivities (up to 70% ee). Cyclic ketones are also reduced with high levels of stereoselectivity with PMHS in the presence of TBAF and baker's yeast, in particular 4-methylcyclohaxanone (trans: cis 84:16). High stereoselectivity is also observed in the reduction of 2-cyanobenzaldehyde and anti- imine was obtained in 71%. | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartofseries | 2012; | - |
dc.subject | asymmetric reduction | en_US |
dc.subject | biocatalyst | en_US |
dc.subject | backer's yeast | en_US |
dc.subject | TBAF | en_US |
dc.subject | PMHS | en_US |
dc.title | The asymmetric reduction of prochiral ketones using tetrabutylammonium fluoride, polymethylhydrosiloxane and biocatalysts, baker's yeast | en_US |
dc.type | Article | en_US |
Appears in Collections: | 1. Faculté des mathématiques et des sciences de la matière |
Files in This Item:
File | Description | Size | Format | |
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M.S.NEDJIMI.pdf | 93,9 kB | Adobe PDF | View/Open |
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