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|Title:||ANODIC BEHAVIOUR INVESTIGATION OF (FERROCENYLMETHYL) TRIMETHYLAMMONIUM CATION|
|Series/Report no.:||volume 1 numéro 2 AST 2007;|
|Abstract:||The quaternary ammonium salt (ferrocenylmethyl)trimethylammonium iodide 4 containing an amminomethyl group has been prepared by the amminomethylation of ferrocene 1 with the Mannich reagent followed by quaternisation with iodomethane. The obtained tertiary ammine 3 and its methiodide 4 have been characterized by FTIR, 1H NMR and 13C NMR. Their electrochemical behaviours have been investigated by cyclic voltammetry, indicating that the quaternary salt 4 exhibit reversible one-electron oxidations of the ferrocene moiety, which is influenced by the aminomethyl group introduced to the ferrocene centre. The same remakes were observed even at slow scan rates.|
|Description:||AST Annales des Sciences et Technologie|
|Appears in Collections:||volume 1 numéro 2 AST 2007|
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