ETUDE STRUCTURALE D¢UN COMPLEXE TÉTRANUCLÉAIRE TRI-THIO FER CARBONYLE :[FE(CO)3]4[S-C(CH3)=C(CH3)-CS2 PRÉSENTANT DES PONTS FER-FER ET FER-SOUFRE

Abstract

Among the coordination compounds of transitions metals, carbonyl metals represent a group of molecules particularly studied because of the richness of their properties and the variety of their filiations. These compounds are used currently more and more in the synthesis of new molecular buildings which present interesting electronic properties in chemistry of coordination.

The objective of this study initially consists in seeking ligands being able to be grafted easily on organic molecules likely to lead to complexes with iron carbonyl.